Effect of Heat on Salts

 
6.10  Effects of Heat on Salts
 
Definition
Chemical method to determine the substances present in a compound through chemical tests.
 
The image is an educational graphic about identifying cations and anions through physical properties. It lists five methods: 1. Colour of salt 2. Solubility of salt 3. Gas test 4. Effect of heat on the salt 5. Confirmatory test for cations The background is white with blue and red accents, and there's a logo at the bottom right corner.
 
Gas Test
  • The process of heating salt may dissociate the salt to release a certain type of gas.
  • The gas can be identified through several tests as below:
 
Gas Confirmatory Test
Oxygen gas
  • Lights up a glowing wooden splinter
Hydrogen gas
  • Produces a ‘pop’ sound with a lighted wooden splinter
Carbon dioxide gas
  • Turns limewater cloudy
Ammonia gas
  • Turns a moist red litmus paper blue
  • Produces thick white fumes with hydrogen chloride gas
Chlorine gas
  • Bleaches a moist red litmus paper
  • Turns a moist blue litmus paper red, then bleaches it
Hydrogen chloride gas
  • Produces thick white fumes with ammonia gas
Nitrogen dioxide gas
  • Turns a moist blue litmus paper red
Sulphur dioxide gas
  • Decolourises an acidified potassium manganate(VII) solution
Water vapour
  • Turns the white anhydrous copper(II) sulphate blue
  • Turns the blue cobalt(II) chloride paper pink
 
Effect of Heat on Carbonate Salt
Colour Before Heating Colour After Heating Effect of Heat
\(K_2CO_3\) Does not decompose by heat
White -
\(Na_2CO_3\)
White -
\(CaCO_3\) Formed metal oxide and carbon dioxide gas
White White
\(MgCO_3\)
White White
\(Al_2(CO_3)_3\)
White White
\(ZnCO_3\)
White Yellow when hot
White when cool
\(FeCO_3\)
Green Green
\(Fe_2(CO_3)_3\)
Brown Brown
\(SnCO_3\)
White White
\(PbCO_3\)
White Brown when hot
Yellow when cool
\(CuCO_3\)
Green Black
\(HgCO_3\)
White Grey
\(Ag_2CO_3\) Formed a metal, carbon dioxide gas and oxygen gas
White Shiny grey
\(Au_2(CO_3)_3\)
White Golden yellow
 
Effect of Heat on Nitrate Salt
Colour Before Heating Colour After Heating Effect of Heat
\(KNO_3\) Formed nitrite salt and oxygen gas
Putih White
\(NaNO_3\)
White White
\(Ca(NO_3)_2\) Formed metal oxide, nitrogen dioxide gas and oxygen gas
White White
\(Mg(NO_3)_2\)
White White
\(Al(NO_3)_3\)
White White
\(Zn(NO_3)_2\)
White Yellow when hot
White when cool
\(Fe(NO_3)_2\)
Green Green
\(Fe(NO_3)_3\)
Brown Brown
\(Sn(NO_3)_2\)
White White
\(Pb(NO_3)_2\)
White Brown when hot
Yellow when cool
\(Cu(NO_3)_2\)
Blue Hitam
\(Hg(NO_3)_2\) Formed metal, nitrogen dioxide gas and oxygen gas
White Grey
\(AgNO_3\)
White Shiny grey
\(Au(NO_3)_3\)
White Golden yellow
 
Colour of Salt
Colour in solid state Colour in solution

Salts of \(Ca^{2+}, Mg^{2+}, Al^{3+}, Pb^{2+}, NH_4\,^{+}\)

White Colourless

\(CuSO_4\)\(Cu(NO_3)_2\)

Blue

\(CuCl_2\)

Green Blue

Salts of ion ferum(II), \(Fe^{2+}\)

Green

Salts of ion ferum(III), \(Fe^{3+}\)

Brown Yellow/ brownish-yellow (depending on the concentration)
 

 

 

 

 

 

 

Effect of Heat on Salts

 
6.10  Effects of Heat on Salts
 
Definition
Chemical method to determine the substances present in a compound through chemical tests.
 
The image is an educational graphic about identifying cations and anions through physical properties. It lists five methods: 1. Colour of salt 2. Solubility of salt 3. Gas test 4. Effect of heat on the salt 5. Confirmatory test for cations The background is white with blue and red accents, and there's a logo at the bottom right corner.
 
Gas Test
  • The process of heating salt may dissociate the salt to release a certain type of gas.
  • The gas can be identified through several tests as below:
 
Gas Confirmatory Test
Oxygen gas
  • Lights up a glowing wooden splinter
Hydrogen gas
  • Produces a ‘pop’ sound with a lighted wooden splinter
Carbon dioxide gas
  • Turns limewater cloudy
Ammonia gas
  • Turns a moist red litmus paper blue
  • Produces thick white fumes with hydrogen chloride gas
Chlorine gas
  • Bleaches a moist red litmus paper
  • Turns a moist blue litmus paper red, then bleaches it
Hydrogen chloride gas
  • Produces thick white fumes with ammonia gas
Nitrogen dioxide gas
  • Turns a moist blue litmus paper red
Sulphur dioxide gas
  • Decolourises an acidified potassium manganate(VII) solution
Water vapour
  • Turns the white anhydrous copper(II) sulphate blue
  • Turns the blue cobalt(II) chloride paper pink
 
Effect of Heat on Carbonate Salt
Colour Before Heating Colour After Heating Effect of Heat
\(K_2CO_3\) Does not decompose by heat
White -
\(Na_2CO_3\)
White -
\(CaCO_3\) Formed metal oxide and carbon dioxide gas
White White
\(MgCO_3\)
White White
\(Al_2(CO_3)_3\)
White White
\(ZnCO_3\)
White Yellow when hot
White when cool
\(FeCO_3\)
Green Green
\(Fe_2(CO_3)_3\)
Brown Brown
\(SnCO_3\)
White White
\(PbCO_3\)
White Brown when hot
Yellow when cool
\(CuCO_3\)
Green Black
\(HgCO_3\)
White Grey
\(Ag_2CO_3\) Formed a metal, carbon dioxide gas and oxygen gas
White Shiny grey
\(Au_2(CO_3)_3\)
White Golden yellow
 
Effect of Heat on Nitrate Salt
Colour Before Heating Colour After Heating Effect of Heat
\(KNO_3\) Formed nitrite salt and oxygen gas
Putih White
\(NaNO_3\)
White White
\(Ca(NO_3)_2\) Formed metal oxide, nitrogen dioxide gas and oxygen gas
White White
\(Mg(NO_3)_2\)
White White
\(Al(NO_3)_3\)
White White
\(Zn(NO_3)_2\)
White Yellow when hot
White when cool
\(Fe(NO_3)_2\)
Green Green
\(Fe(NO_3)_3\)
Brown Brown
\(Sn(NO_3)_2\)
White White
\(Pb(NO_3)_2\)
White Brown when hot
Yellow when cool
\(Cu(NO_3)_2\)
Blue Hitam
\(Hg(NO_3)_2\) Formed metal, nitrogen dioxide gas and oxygen gas
White Grey
\(AgNO_3\)
White Shiny grey
\(Au(NO_3)_3\)
White Golden yellow
 
Colour of Salt
Colour in solid state Colour in solution

Salts of \(Ca^{2+}, Mg^{2+}, Al^{3+}, Pb^{2+}, NH_4\,^{+}\)

White Colourless

\(CuSO_4\)\(Cu(NO_3)_2\)

Blue

\(CuCl_2\)

Green Blue

Salts of ion ferum(II), \(Fe^{2+}\)

Green

Salts of ion ferum(III), \(Fe^{3+}\)

Brown Yellow/ brownish-yellow (depending on the concentration)